CH4+2O2-to>CO2+2H2O

x---------2x-------x

C2H4+3O2-to>2CO2+2H2O

y-------------3y------2y

=>Ta có :

\(\left\{{}\begin{matrix}x+y=0,04\\2x+3y=0,11\end{matrix}\right.\)

=>x=0,01, y=0,03 mol

=>%VCH4=\(\dfrac{0,01.22,4}{0,896}100\)=25%

=>%VC2H4=75%

=>m CO2=(0,01+0,03.2).44=3,08g

a, ta có PTHH : 

CH₄ + 2O₂ \(\Rightarrow\) CO₂ + 2H₂O (*)

C₂H₄ + 3O₂ \(\Rightarrow\) 2CO₂ + 2H₂O(+)

b, Gọi x, y lần lượ là số mol của CH₄ , C₂H₄ ( x, y > 0 )

Ta có : n_{h =} \(\dfrac{0,896}{22,4}=0,04\left(mol\right)\)

\(\Rightarrow x+y=0,04\left(mol\right)\) (1)

lại có n_{o2 pứ} = \(\dfrac{3,52}{32}=0,11\left(mol\right)\)

\(\Rightarrow2x+3y=0,11\left(mol\right)\) (2)

Từ (1) và (2) ta có hệ pt:\(\left\{{}\begin{matrix}x+y=0,04\\2x+3y=0,11\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,01\left(mol\right)\\y=0,03\left(mol\right)\end{matrix}\right.\)

%V_CH4 = \(\dfrac{0,01}{0,04}\times100\%=25\%\)

%V_C2H4 = \(\dfrac{0,03}{0,04}\times100\%=75\%\)

c, Theo pt n_CO2(*) = n_CH4 = 0,01 (mol)

n_CO2(+) = 2n_C2H4 = 0,6 (mol)

\(\Rightarrow m_{co_2}=\left(0,01+0,6\right)\times44=26,84\left(g\right)\)

Bài 1 : 

Giả sử : hỗn hợp có 1 mol 

\(n_{H_2}=a\left(mol\right),n_{O_2}=1-a\left(mol\right)\)

\(\overline{M_X}=0.3276\cdot29=9.5\left(\dfrac{g}{mol}\right)\)

\(\Rightarrow m_X=2a+32\cdot\left(1-a\right)=9.5\left(g\right)\)

\(\Rightarrow a=0.75\)

Cách 1 : 

\(\%H_2=\dfrac{0.75}{1}\cdot100\%=75\%\)

\(\%O_2=100-75=25\%\)

Cách 2 em tính theo thể tích nhé !

Bài 2 : 

\(M_A=16\cdot4=64\left(\dfrac{g}{mol}\right)\)

\(n_A=\dfrac{16}{64}=0.25\left(mol\right)\)

\(V_A=0.25\cdot22.4=5.6\left(l\right)\)

Bài 3 : 

\(M_A=16\cdot2.75=44\left(\dfrac{g}{mol}\right)\)

\(M_B=M_A\cdot1.4545=44\cdot1.4545=64\left(\dfrac{g}{mol}\right)\)

CH4+2O2-to>CO2+2H2O

x---------2x-------x---------2x

C2H4+3O2-to>2CO2+2H2O

y-------------3y------2y-------2y

=>\(\left\{{}\begin{matrix}16x+28y=1,36\\2x+3y=0,16\end{matrix}\right.\)

=>x=0,05 mol , y=0,02 mol

=>%m CH4=\(\dfrac{0,05.16}{1,36}100\)=58,82%

=>%m C2H4=41,17%

=>mH2O=(0,1+0,04).18=2,52g

a, \(n_{O_2}=\dfrac{3,584}{22,4}=0,16\left(mol\right)\)

PTHH: CH₄ + 2O₂ ---t^o→ CO₂ + 2H₂O

Mol:       x        2x                           2x

PTHH: C₂H₄ + 3O₂ ---t^o→ 2CO₂ + 2H₂O

Mol:        y         3y                               2y

b,Ta có hệ pt: \(\left\{{}\begin{matrix}16x+28y=1,36\\2x+3y=0,16\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,05\left(mol\right)\\y=0,02\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{CH_4}=0,05.16=0,8\left(g\right)\Rightarrow\%m_{CH_4}=\dfrac{0,8.100\%}{1,36}=58,82\%\)

\(\Rightarrow\%m_{C_2H_4}=100\%-58,82\%=41,18\%\)

c, \(m_{H_2O}=\left(2.0,05+2.0,02\right).18=2,52\left(g\right)\)

1.1. Al + NaOH + H2O ==> NaAlO2 + 3/2H2

nH2(1)=3,36/22,4=0.15(mol)

=> nAl(1)= nH2(1):3/2= 0.15:3/2= 0.1(mol)

2.Mg + 2HCl ==> MgCl2 + H2

3.2Al + 6HCl ==> 2AlCl3 + 3H2

4.Fe + 2HCl ==> FeCl2 + H2

=> \(n_{H_2\left(2,3,4\right)}=\) 10.08/22.4= 0.45(mol)

=> nH2(3)=0.1*3/2=0.15(mol)

MgCl2 + 2NaOH ==> Mg(OH)2 + 2NaCl

AlCl3 + 3NaOH ==> Al(OH)3 + 3NaCl

FeCl2 + 2NaOH ==> Fe(OH)2 + 2NaCl

- Thấy tỉ lệ số phân tử cũng là tỉ lệ mol .

a, Ta có : \(\dfrac{n_{CO}}{1}=\dfrac{n_{CO2}}{2}=\dfrac{n_{SO_2}}{5}\)

Mà tổng số mol = \(\dfrac{V}{22,4}=3,2\left(mol\right)\)

- Áp dụng dãy tính chất tỉ số bằng nhau :

\(\Rightarrow\left\{{}\begin{matrix}n_{CO}=0,4\\n_{CO_2}=0,8\\n_{SO_2}=2\end{matrix}\right.\) mol

\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=11,2\\m_{CO_2}=35,2\\m_{SO_2}=128\end{matrix}\right.\) ( g )

b, Ta có : \(\overline{M_Y}=\dfrac{m}{n}=54,5\)

\(\Rightarrow d_{\dfrac{y}{kk}}=~1,9\)

a)

Gọi $n_{CO} = a(mol) \to n_{CO_2} = 2a(mol) ; n_{SO_2} = 5a(mol)$

Ta có :

$a+ 2a + 5a = \dfrac{71,68}{22,4} = 3,2$
$\Rightarrow a = 0,4(mol)$

$m_{CO} = 0,4.28 = 11,2(gam)$
$m_{CO_2} = 0,4.2.44 = 35,2(gam)$
$m_{SO_2} = 0,4.5.64 = 128(gam)$
b)

$M_Y = \dfrac{11,2 + 35,2 + 128}{3,2} = 54,5(g/mol)$
$d_{Y/kk} = \dfrac{54,5}{29} = 1,88$

Tỉ lệ số phân tử chính là tỉ lệ số mol. 

\(n_{CO}=x\left(mol\right),n_{CO_2}=2x\left(mol\right),n_{SO_2}=5x\left(mol\right)\)

\(n_Y=\dfrac{71.68}{22.4}=3.2\left(mol\right)\)

\(\Leftrightarrow8x=3.2\)

\(\Leftrightarrow x=0.4\)

\(m_{CO}=0.4\cdot28=11.2\left(g\right)\)

\(m_{CO_2}=0.8\cdot44=35.2\left(g\right)\)

\(m_{SO_2}=2\cdot64=128\left(g\right)\)

\(b.\)

\(\overline{M}=\dfrac{11.2+35.2+128}{3.2}=54.5\left(\dfrac{g}{mol}\right)\)

nO₂ = \(\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Pt: 2Cu + O₂ \(\rightarrow\) 2CuO

        x       0,5x        x

      3Fe + 2O₂ \(\rightarrow\) Fe₃O₄

        y          2/3y      1/3y

Theo bài ta có hpt: 

\(\left\{{}\begin{matrix}64x+56y=23,2\\0,5x+\dfrac{2}{3}y=0,25\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}x=0,1\\y=0,3\end{matrix}\right.\)

mCuO = 0,1.80 = 8 g

mFe₃O₄ = 0,3.232 = 69,6g

=> %mCuO = \(\dfrac{8}{8+69,6}.100\%=10,3\%\)

%mFe₃O₄ = 100 - 10,3 = 89,7%

a, Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH:

Fe + 2HCl ---> FeCl₂ + H₂

a--->2a------------------>a

2Al + 6HCl ---> 2AlCl₃ + 3H₂

b---->3b-------------------->1,5b

=> \(\left\{{}\begin{matrix}56a+27b=16,6\\a+1,5b=0,5\end{matrix}\right.\Leftrightarrow a=b=0,2\left(mol\right)\)

=> \(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)

b) \(C\%_{HCl}=\dfrac{\left(0,2.2+0,2.3\right).36,5}{300}.100\%=12,167\%\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) 
gọi nFe : a , nAl: b (a,b>0)  => 56a + 27b = 16,6 (g) 
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\) 
           a                                     a
         \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\) 
           b                                     \(\dfrac{3b}{2}\)
          
=> \(a+\dfrac{3b}{2}=0,5\) 
ta có hệ pt 
\(\left\{{}\begin{matrix}56a+27b=16,6\\a+\dfrac{3b}{2}=0,5\end{matrix}\right.\) 
=> a= 0,2 , b = 0,2 
\(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=16,6-11,2=5,4\left(g\right)\end{matrix}\right.\) 
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\) 
           0,2     0,4 
        \(2Al+6HCl\rightarrow2AlCl_3+3H_2\) 
           0,2    0,6 
=> \(m_{HCl}=\left(0,4+0,6\right).36,5=36,5\left(g\right)\) 
=> \(C\%=\dfrac{36,5}{200}.100\%=18,25\%\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: Ba + 2H₂O --> Ba(OH)₂ + H₂

          0,1<------------------------0,1

=> m_Ba = 0,1.137 = 13,7 (g)

=> m_Cu = 20 - 13,7 = 6,3 (g)

\(\left\{{}\begin{matrix}\%m_{Ba}=\dfrac{13,7}{20}.100\%=68,5\%\\\%m_{Cu}=\dfrac{6,3}{20}.100\%=31,5\%\end{matrix}\right.\)

Ba+2H₂O->Ba(OH)₂+H₂

0,1--------------------------0,1 mol

n _H2 =\(\dfrac{2,24}{22,4}=0,1mol\)

m _Ba=0,1.137=13,7g=>%Ba=68,5%

=>m _Cu=20-13,7=6,3g=>%Cu=31,5%

Vik chỉ có Ba tác dụng đc vs nước (H₂O) , Cu ko td vs nước nên ta có :

PTHH :  \(Ba+2H_2O->Ba\left(OH\right)_2+H_2\uparrow\)       (1)

\(n_{H_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Từ (1) ->  \(n_{Ba}=n_{H_2}=0,1\left(mol\right)\)

-> \(m_{Ba}=n.M=0,1.137=13,7\left(g\right)\)

=> \(\%m_{Ba}=\dfrac{m_{Ba}}{m_{HH}}.100\%=68,5\%\)

\(\%m_{Cu}=100\%-\%m_{Ba}=100\%-68,5\%=31,5\%\)